Presenter Information

Elizabeth CumminsFollow

Presentation Title

New Reactions of Strained Allyl Silacycles

Presentation Type

Poster

Abstract

Ring-strained allylsilanes exhibit both electrophilic and nucleophilic characteristics, allowing for simultaneous activation and allylation of carbonyl compounds. Results are presented describing an optimized synthesis of certain allylsilacyclobutanes and their use in several selective carbon-carbon bond forming reactions.

Start Date

10-5-2018 12:00 PM

End Date

10-5-2018 2:00 PM

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May 10th, 12:00 PM May 10th, 2:00 PM

New Reactions of Strained Allyl Silacycles

Ring-strained allylsilanes exhibit both electrophilic and nucleophilic characteristics, allowing for simultaneous activation and allylation of carbonyl compounds. Results are presented describing an optimized synthesis of certain allylsilacyclobutanes and their use in several selective carbon-carbon bond forming reactions.