Cycling of ethanol and acetaldehyde in coastal waters

Research Mentor(s)

Catherine Clark

Description

The short-term goal of this work is to improve our understanding of ethanol and acetaldehyde cycling in coastal waters. Increased use of ethanol as a fossil fuel substitute and additive is expected to have an impact on atmospheric levels of both ethanol and acetaldehyde. To understand future impacts, we need to understand current tropospheric budgets. One of the largest sources of uncertainty in budget estimates is the role of the oceans and surface waters in cycling these species into or out of the troposphere. Concentrations of ethanol and acetaldehyde in water are controlled primarily by biological degradation and photochemical production. Measurements of these production and destruction rates will help constrain estimates of air-water exchange of these species. Here we report measurements of ethanol and acetaldehyde biological degradation rates, and photochemical production rates at three sites in a classic Southern Californian estuary. We also report measurements of a dark ethanol to acetaldehyde biological conversion process.

Document Type

Event

Start Date

May 2022

End Date

May 2022

Location

Carver Gym (Bellingham, Wash.)

Department

CSE - Chemistry

Genre/Form

student projects; posters

Type

Image

Rights

Copying of this document in whole or in part is allowable only for scholarly purposes. It is understood, however, that any copying or publication of this document for commercial purposes, or for financial gain, shall not be allowed without the author’s written permission.

Language

English

Format

application/pdf

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May 18th, 9:00 AM May 18th, 5:00 PM

Cycling of ethanol and acetaldehyde in coastal waters

Carver Gym (Bellingham, Wash.)

The short-term goal of this work is to improve our understanding of ethanol and acetaldehyde cycling in coastal waters. Increased use of ethanol as a fossil fuel substitute and additive is expected to have an impact on atmospheric levels of both ethanol and acetaldehyde. To understand future impacts, we need to understand current tropospheric budgets. One of the largest sources of uncertainty in budget estimates is the role of the oceans and surface waters in cycling these species into or out of the troposphere. Concentrations of ethanol and acetaldehyde in water are controlled primarily by biological degradation and photochemical production. Measurements of these production and destruction rates will help constrain estimates of air-water exchange of these species. Here we report measurements of ethanol and acetaldehyde biological degradation rates, and photochemical production rates at three sites in a classic Southern Californian estuary. We also report measurements of a dark ethanol to acetaldehyde biological conversion process.