Presenter Information

Gabriel BourneFollow

Presentation Title

Synthesis and metallation of a novel stimulus responsive ligand

Presentation Type

Poster

Abstract

Bidentate ligands in which the coordinated atoms are linked by an ethylene glycol chain can change their conformation in response to the stimulus of a small cation. With the goal of using such a conformation change to promote oxidative addition at Au(I), a novel LX-type with an ethylene glycol linker was prepared. The multi-step ligand synthesis and initial metallation efforts will be presented.

Start Date

10-5-2018 12:00 PM

End Date

10-5-2018 2:00 PM

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May 10th, 12:00 PM May 10th, 2:00 PM

Synthesis and metallation of a novel stimulus responsive ligand

Bidentate ligands in which the coordinated atoms are linked by an ethylene glycol chain can change their conformation in response to the stimulus of a small cation. With the goal of using such a conformation change to promote oxidative addition at Au(I), a novel LX-type with an ethylene glycol linker was prepared. The multi-step ligand synthesis and initial metallation efforts will be presented.